Highlights The robust organic/inorganic hybrid interlayer derived from in situ formed tribofilms were fabricated by using a scalable rolling method.The interlayer facilitates dendrite-free lithium metal anodes by building local de-solvation environments near the interface and LED Power Suppliers inhibiting both dendrite growth and electrolytes corrosion.The symmetrical cell exhibits a remarkable lifespan of 5,600 h (1.
0 mA cm-2 and 1.0 mAh cm-2) Castor and 1,350 cycles even at a harsh condition (18.0 mA cm-2 and 3.
0 mAh cm-2).